Understanding Battery Failure in Realtime, at the Nanoscale

Understanding Battery Failure in Realtime, at the Nanoscale

Aluminum has many qualities that should make it a suitable material for use in ultra-light and on-chip batteries: it has a high melting point, high conductivity, and low cost.

“It would be a great anode for lithium-ion batteries,” says University of Maryland assistant professor Marina Leite, “if only we could stop it from reacting with lithium ions in a way that quickly ruins them. If we want to solve this problem, we need to understand why and how aluminum anodes fail.”

Leite, a member of the Department of Materials Science and Engineering and the Institute for Research in Applied Physics is part of a team that created a new way to probe the degradation of an entire aluminum anode, in realtime and at nanoscale resolution, using a combination of electron microscopy techniques. What she and her colleagues discovered could give battery developers the insight they need for future success.

All solid-state lithium-ion (Li-ion) batteries require anodes, positively charged electrodes that attract lithium ions during the charging process. These anodes have a “breathing” mechanism: their volume expands by the addition of lithium ions as the battery is being charged, a process called lithiation, then contracts as the ions diffuse back to the positive electrode during discharge, or delithiation process. The anodes must remain stable and able to withstand repeated cycles of charging and discharging without being pulverized in the process.

Prior studies that attempted to explain aluminum anode failure suggested that they either crumbled, which has been observed in other anode materials, or that high strain caused the formation of a stiff aluminum-lithium alloy (AlLi) in the aluminum’s matrix, which ruined its ability to expand and contract properly. Leite and her colleagues devised a way to find out if either of these theories were correct.

“The usual procedure is to take microscopy ‘snapshots' of the anode material before and after cycling the battery,” she explains. “We used a scanning electron microscope to image the changes taking place at the anode while charging and discharging the battery, which established a direct correlation between the structural changes in the material and the electrochemistry.”

Using the new observation technique, Leite and her team discovered that aluminum anode failure is actually caused by lithium reacting with aluminum to form tiny "mounds" on the surface of the aluminum. These structures both permanently trap lithium and block still-free lithium ions from participating in the charge/discharge cycle. The anode’s surface compounded the problem.

“The main challenge of working with aluminum is that a thin layer of aluminum oxide naturally forms on its surface,” says Leite. “In our case, it plays a critical role in the degradation of the battery. When it reacts with the lithium, it forms a very stable alloy, aluminum lithium oxide. The alloy surrounds the mounds, like a prison wall around locked cells. Ultimately, this creates a tough barrier for any remaining lithium ions.”

Without sufficient lithiation and delithiation, the battery’s performance is limited, and since lithium diffuses through aluminum very quickly at room temperature, it doesn’t take long for all these reactions to take place.

Leite’s group is now exploring ways to address these problems, such as developing conductive thin films that will, when applied to surface of an aluminum anode, reduce oxidation and boost the battery’s capacity. The team also hopes to test their observation technique on other battery materials.

A paper describing the observation technique and results of the study was published in the Journal of Materials Chemistry A, where it was also featured on the publication’s inside cover.

For More Information:

See: Marina S. Leite, Dmitry Ruzmetov, Zhipeng Li, Leonid A. Bendersky, Norman C. Bartelt, Andrei Kolmakov and A. Alec Talin. Insights into capacity loss mechanisms of all-solid-state Li-ion batteries with Al anodes. J. Mater. Chem. A, 2014, 2, 20552. View online

Visit the Leite Lab web site

February 23, 2015


Prev   Next

Current Headlines

UMD Leads New $25M NSF Quantum Leap Challenge Institute for Robust Quantum Simulation

Michael Fu Works to Improve Kidney Transplants With NSF Grant

IonQ Joins University of Maryland Quantum Startup Foundry, Receives National Innovation Award

Entomology and Extension Faculty Join a National Team to Study and Support Diverse Perennial Forage Systems with Major Implications for Human and Animal Ecosystem Health

Sangeetha Madhavan Publishes New Research On Families’ Economic Inequalities In Sub-Saharan Africa

Technology for All

Center for Substance Abuse Research Receives Funding to Expand the Emergency Department Drug Surveillance System Nationwide

Student Journalism Project Sheds Light on Role of White Supremacist Newspapers in Fueling Racial Tension, Violence

News Resources

Return to Newsroom

Search News

Archived News

Events Resources

Events Calendar

Additional Resources

UM Newsdesk

Faculty Experts

Connect

social iconstwitterlinkedinrssYouTube
Division of Research
University of Maryland
College Park, MD 20742-1541
© Copyright 2021 University of Maryland

Did You Know

UMD is home to more than 40,700 students, 14,000 faculty and staff, and 300 academic programs.